Title:
Distance-Dependent Electron Transfer Kinetics in Axially Connected Silicon Phthalocyanine-Fullerene Conjugates |
Authors:
Martín-Gomis, Luis
Seetharaman, Sairaman
Herrero, David
Karr, Paul A.
Fernández-Lázaro, Fernando
D'Souza, Francis
Sastre-Santos, Ángela |
Editor:
Wiley |
Department:
Departamentos de la UMH::Farmacología, Pediatría y Química Orgánica |
Issue Date:
2020-10 |
URI:
https://hdl.handle.net/11000/37910 |
Abstract:
The effect of donor-acceptor distance in controlling the rate of
electron transfer in axially linked silicon phthalocyanine-C60
dyads has been investigated. For this, two C60-SiPc-C60 dyads, 1
and 2, varying in their donor-acceptor distance, have been
newly synthesized and characterized. In the case of C60-SiPc-C60
1 where the SiPc and C60 are separated by a phenyl spacer,
faster electron transfer was observed with kcs equal to 2.7×
109 s
|
Knowledge area:
CDU: Ciencias aplicadas: Medicina: Farmacología. Terapéutica. Toxicología. Radiología |
Type of document:
info:eu-repo/semantics/article |
Access rights:
info:eu-repo/semantics/openAccess
Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
DOI:
https://doi.org/10.1002/cphc.202000578 |
Published in:
ChemPhyschem, Volume21, Issue 20, (2020) |
Appears in Collections:
Artículos Farmacología, Pediatría y Química Orgánica
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