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dc.contributor.authorZink Lorre, Nathalie-
dc.contributor.authorFont-Sanchis, Enrique-
dc.contributor.authorSeetharaman, Sairaman-
dc.contributor.authorKarr, Paul A.-
dc.contributor.authorSastre-Santos, Ángela-
dc.contributor.authorD’Souza, Francis-
dc.contributor.authorFernández Lázaro, Fernando-
dc.contributor.otherDepartamentos de la UMH::Farmacología, Pediatría y Química Orgánicaes_ES
dc.date.accessioned2024-02-05T11:43:08Z-
dc.date.available2024-02-05T11:43:08Z-
dc.date.created2019-
dc.identifier.citationChemistry A European Journal. 2019 Aug 1;25(43):10123-10132es_ES
dc.identifier.issn1521-3765-
dc.identifier.issn0947-6539-
dc.identifier.urihttps://hdl.handle.net/11000/31047-
dc.description.abstractDirectly linked to promote strong intramolecular interactions, donor-acceptor dyads and a donor-acceptor-donor triad featuring zinc phthalocyanine (ZnPc) as electron donor and perylenediimide (PDI) as electron acceptor have been synthesized and characterized. Owing to complementary absorption features of the entities, improved light absorption was witnessed in these conjugates. The optimized geometry and electronic structures showed the majority of the highest occupied molecular orbital (HOMO) on the ZnPc entity, whereas the lowest unoccupied molecular orbital (LUMO) was on the PDI entity, suggesting that the charge-separated states would be ZnPc+ -PDI. - . The electrochemical and free-energy calculations suggested exothermic energy and/or electron transfer processes via the singlet states of PDI or ZnPc entities depending on the excitation wavelength of the laser used. The measured rates using femtosecond pump-probe spectroscopy coupled with global analysis of transient data revealed ultrafast energy transfer from 1 PDI* to ZnPc followed by charge separation. However, when ZnPc was selectively excited, only electron transfer was witnessed wherein the time constants for forward and reverse electron transfer processes followed Marcus predictions. The absorption in a wide section of the solar spectrum and the ultrafast charge separation suggest the usefulness of these systems as good photosynthetic models.es_ES
dc.formatapplication/pdfes_ES
dc.format.extent10es_ES
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.rightsinfo:eu-repo/semantics/closedAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectcharge separationes_ES
dc.subjectdonor-acceptor conjugateses_ES
dc.subjectexcitation transferes_ES
dc.subjectperylenediimidees_ES
dc.subjectzinc phthalocyanine.es_ES
dc.titleDirectly Linked Zinc Phthalocyanine–Perylenediimide Dyads and a Triad for Ultrafast Charge Separationes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.contributor.instituteInstitutos de la UMH::Instituto de Bioingenieríaes_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201900973es_ES
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Artículos Farmacología, Pediatría y Química Orgánica


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