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Effect of Substituents at Imide Positions on the Laser Performance of 1,7-Bay-Substituted Perylenediimide Dyes

Título :
Effect of Substituents at Imide Positions on the Laser Performance of 1,7-Bay-Substituted Perylenediimide Dyes
Autor :
Muñoz-Mármol, Rafael  
Boj, Pedro G.
Villalvilla, José M.
Quintana, José A.
Zink Lorre, Nathalie
Sastre-Santos, Ángela
Aragó, Juan  
Ortí, Enrique
Baronas, Paulius  
Litvinas, Džiugas  
Jursenas, Saulius
Fernández Lázaro, Fernando
Díaz-García, María A.
Editor :
American Chemical Society
Departamento:
Departamentos de la UMH::Farmacología, Pediatría y Química Orgánica
Fecha de publicación:
2021
URI :
https://hdl.handle.net/11000/31039
Resumen :
Perylenediimide (PDI) compounds with no substituents in their core are widely used as the active units of thin-film organic lasers. Recently, baysubstituted PDIs (b-PDIs) bearing two sterically hindering diphenylphenoxy groups at the 1,7-bay positions have received great attention because they show red-shifted emission with respect to bay-unsubstituted PDIs, while maintaining high photoluminescence (PL) quantum yields and low amplified spontaneous emission (ASE) thresholds even at high doping rates. However, their ASE photostability is relatively low compared to that of state-of-the-art PDIs. Thus, the design of b-PDIs with improved ASE photostability remains a challenge. Here, the synthesis of two b-PDIs with phenyl-type substituents at the imide positions is reported. Complete characterization of their optical properties, including absorption, PL, ASE, and transient spectroscopy, supported also by quantum chemical calculations, is performed with the dyes diluted in either a liquid solvent or a polystyrene film. Film experiments were accomplished at very low doping rates, to resemble the isolated molecule behavior, and also in a range of increasing doping rates, to investigate concentration quenching effects. The reported b-PDIs show improved ASE photostability (3- fold) with respect to b-PDIs with aliphatic-type substituents at the imide positions, whilst they show more propensity toward aggregation.
Tipo documento :
application/pdf
Derechos de acceso:
info:eu-repo/semantics/openAccess
DOI :
https://doi.org/10.1021/acs.jpcc.1c00833
Aparece en las colecciones:
Artículos Farmacología, Pediatría y Química Orgánica



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