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https://hdl.handle.net/11000/40843
Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion
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Title:
Formation of a long-lived charge-separated state of a zinc phthalocyanine-perylenediimide dyad by complexation with magnesium ion |
Authors:
Fukuzumi, Shunichi
Ohkubo, Kei
Ortiz, Javier
Gutiérrez, Ana Mª
Fernández-Lázaro, Fernando
Sastre-Santos, Ángela |
Editor:
Royal Society of Chemistry |
Department:
Departamentos de la UMH::Farmacología, Pediatría y Química Orgánica |
Issue Date:
2005-06 |
URI:
https://hdl.handle.net/11000/40843 |
Abstract:
Photoexcitation of a zinc phthalocyanine–perylenediimide (ZnPc–PDI) dyad affords the triplet excited state without the fluorescence emission, whereas addition of Mg2+ to the photoexcited ZnPc–PDI results in formation of a long-lived charge-separated state (ZnPc˙+–PDI˙−/Mg2+) in which PDI˙− forms a complex with Mg2+.
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Keywords/Subjects:
photoexcitation
zinc phthalocyanine–perylenediimide
Mg2+ |
Knowledge area:
CDU: Ciencias puras y naturales: Química |
Type of document:
info:eu-repo/semantics/article |
Access rights:
info:eu-repo/semantics/closedAccess
Attribution-NonCommercial-NoDerivatives 4.0 Internacional |
DOI:
https://doi.org/10.1039/b506412k |
Published in:
Chemical Communications (ChemComm) - Vol. 41, Issue 30 (2005), pp. 3814–3816 |
Appears in Collections:
Artículos - Farmacología, Pediatría y Química Orgánica
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