Easy and mild fluoride-mediated direct mono- and dialkoxylation of perylenediimides

Zink Lorre, Nathalie; Font-Sanchis, Enrique; Sastre-Santos, Ángela; Fernández-Lázaro, Fernando

Please use this identifier to cite or link to this item: https://hdl.handle.net/11000/38042

Easy and mild fluoride-mediated direct mono- and dialkoxylation of perylenediimides

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Title:
Easy and mild fluoride-mediated direct mono- and dialkoxylation of perylenediimides

Authors:
Zink Lorre, Nathalie

Font-Sanchis, Enrique

Sastre-Santos, Ángela

Fernández-Lázaro, Fernando

Editor:
Elsevier

Department:
Departamentos de la UMH::Farmacología, Pediatría y Química Orgánica

Issue Date:
2016-04

URI:
https://hdl.handle.net/11000/38042

Abstract:
The reaction of perylenediimides with alcohols in the presence of fluoride anions yields 1-alkoxy- or 1,6(7)-dialkoxyperylenediimides under very mild metal-free conditions. The reaction can also be applied to bay- and ortho-brominated perylenediimides.

Keywords/Subjects:
Arenes
Dyes/pigments
Aromatic substitution
Radical reaction
Synthetic methods
Perylenediimides

Type of document:
info:eu-repo/semantics/article

Access rights:
info:eu-repo/semantics/closedAccess
Attribution-NonCommercial-NoDerivatives 4.0 Internacional

DOI:
https://doi.org/10.1016/j.dyepig.2015.12.011

Published in:
Dyes and Pigments. Volume 127, April 2016, Pages 9-17

Appears in Collections:
Artículos Farmacología, Pediatría y Química Orgánica

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